X-ray structure analysis of symmetrically substituted 1,1′-diformyl­ruthenocene

Acta Crystallographica Section E: Crystallographic Communications

Anzaldo, B.¹  Sharma, P.² 

[1] Instituto de Qumica Universidad Autnoma de Mxico UNAM, Cd., Universitaria, PO Box 04510, Ciudad de Mxico, Mexico;Lab. Sntesis de Complejos, Fac. Cs. Qum.-BUAP, Ciudad Universitaria, PO Box 72592 Puebla, Mexico

关键词: RUTHENOCENE;    1,1'-DIFORMYLRUTHENOCENE;    X-RAY STRUCTURE;    CRYSTAL STRUCTURE;   

DOI  :  10.1107/S2056989018010642

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

1,1′-Di­formyl­ruthenocene, [Ru(C6H5O)2], crystallizes in the ortho­rhom­bic system in the P212121 space group at room temperature. There are two crystallographically independent mol­ecules in the asymmetric unit. The cyclo­penta­dienyl rings have eclipsed configuration. The mol­ecules self-assemble in a two-dimensional structure by C—H⋯O and C—H⋯π inter­actions with cisoid relative orientations of the two formyl groups. The crystal studied was refined as an inversion twin.

【 授权许可】

CC BY