Crystal structure of bis­(isonicotinamide-κN1)bis­(thio­cyanato-κN)zinc

Acta Crystallographica Section E: Crystallographic Communications

Neumann, T.¹  ther, C.¹  Jess, I.²  Nä³ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    DISCRETE COMPLEX;    ZINC THIOCYANATE;    ISONICOTINAMIDE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989016008963

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn2+ cation located on a twofold rotation axis, as well as of one thio­cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+ cation is tetra­hedrally coordinated into a discrete complex by the N atoms of two symmetry-related thio­cyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by inter­molecular C—H⋯O and N—H⋯O, and weak inter­molecular N—H⋯S hydrogen-bonding inter­actions into a three-dimensional network.

【 授权许可】

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