期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of bis(isonicotinamide-κN1)bis(thiocyanato-κN)zinc | |
Neumann, T.1  ther, C.1  Jess, I.2  Nä3  | |
[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany | |
关键词: CRYSTAL STRUCTURE; DISCRETE COMPLEX; ZINC THIOCYANATE; ISONICOTINAMIDE; HYDROGEN BONDING; | |
DOI : 10.1107/S2056989016008963 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn2+ cation located on a twofold rotation axis, as well as of one thiocyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn2+ cation is tetrahedrally coordinated into a discrete complex by the N atoms of two symmetry-related thiocyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by intermolecular C—H⋯O and N—H⋯O, and weak intermolecular N—H⋯S hydrogen-bonding interactions into a three-dimensional network.
【 授权许可】
CC BY
【 预 览 】
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