Crystal structure of bis­[4-(di­methyl­amino)­pyridine-κN1]bis­(methanol-κO)bis­(thio­cyanato-κN)manganese(II)

Acta Crystallographica Section E: Crystallographic Communications

ther, C.¹  Suckert, S.¹  Jess, I.²  Nä³ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    DISCRETE COMPLEX;    OCTAHEDRAL COORDINATION;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989015007318

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The whole mol­ecule of the title compound, [Mn(NCS)2(CH3OH)2(C5H6N2)2], is generated by inversion symmetry. The MnII ion, which is located on an inversion center, is coordinated by two 4-(di­methyl­amino)­pyridine ligands, two methanol ligands and two terminally N-bonded thio­cyanate anions, forming a slightly distorted octa­hedron. In the crystal, mol­ecules are linked by O—H⋯S hydrogen bonds, forming chains extending along the a-axis direction.

【 授权许可】

CC BY