Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of bis(pyridine-4-carbothioamide-κN1)bis(thiocyanato-κN)cobalt(II) methanol monosolvate | |
Neumann, T.1  ther, C.1  Jess, I.2  Nä3  | |
[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany | |
关键词: CRYSTAL STRUCTURE; DISCRETE COMPLEX; COBALT(II) THIOCYANATE; PYRIDINE-4-CARBOTHIOAMIDE; HYDROGEN BONDING; METHANOL SOLVATE; | |
DOI : 10.1107/S2056989017015055 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The asymmetric unit of the title compound, [Co(NCS)2(C6H6NS)4]·CH3OH, consists of one cobalt(II) cation, two thiocyanate anions, four pyridine-4-carbothioamide ligands and one methanol molecule that are located in general positions. The CoII cations are coordinated by two terminal N-bonding thiocyanate anions and four N-bonding pyridine-4-carbothioamide ligands, resulting in discrete and slightly distorted octahedral complexes. These complexes are linked into a three-dimensional network via intermolecular N—H⋯S hydrogen bonding between the amino H atoms and the thiocyanate and pyridine-4-carbothioamide S atoms. From this arrangement, channels are formed in which the methanol solvate molecules are embedded and linked to the host structure by intermolecular O—H⋯S and N—H⋯O hydrogen bonding.
【 授权许可】
CC BY
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