Crystal structure of bis­(pyridine-4-carbo­thio­amide-κN1)bis­(thio­cyanato-κN)cobalt(II) methanol monosolvate

Acta Crystallographica Section E: Crystallographic Communications

Neumann, T.¹  ther, C.¹  Jess, I.²  Nä³ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    DISCRETE COMPLEX;    COBALT(II) THIOCYANATE;    PYRIDINE-4-CARBOTHIOAMIDE;    HYDROGEN BONDING;    METHANOL SOLVATE;   

DOI  :  10.1107/S2056989017015055

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The asymmetric unit of the title compound, [Co(NCS)2(C6H6NS)4]·CH3OH, consists of one cobalt(II) cation, two thio­cyanate anions, four pyridine-4-carbo­thio­amide ligands and one methanol mol­ecule that are located in general positions. The CoII cations are coordinated by two terminal N-bonding thio­cyanate anions and four N-bonding pyridine-4-carbo­thio­amide ligands, resulting in discrete and slightly distorted octa­hedral complexes. These complexes are linked into a three-dimensional network via inter­molecular N—H⋯S hydrogen bonding between the amino H atoms and the thio­cyanate and pyridine-4-carbo­thio­amide S atoms. From this arrangement, channels are formed in which the methanol solvate mol­ecules are embedded and linked to the host structure by inter­molecular O—H⋯S and N—H⋯O hydrogen bonding.

【 授权许可】

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