Crystal structure of bis­(aceto­nitrile-κN)bis­(4-benzoyl­pyridine-κN)bis­(thio­cyanato-κN)cobalt(II)

Acta Crystallographica Section E: Crystallographic Communications

Werner, J.¹  Jess, I.¹  Suckert, S.¹  Näther, C.¹ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Strasse 2, D-24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    DISCRETE COMPLEX;    COBALT(II) THIOCYANATE;    4-BENZOYLPYRIDINE;    HYDROGEN BONDING;   

DOI  :  10.1107/S2056989017002201

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The crystal structure of the title compound, [Co(NCS)2(C2H3N)2(C12H9NO)2], consists of cobalt(II) cations that are octa­hedrally coordinated by the N atoms of two terminal thio­cyanate anions, two aceto­nitrile mol­ecules and two 4-benzoyl­pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter­molecular C—H⋯O and C—H⋯S hydrogen-bonding inter­actions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the aceto­nitrile mol­ecule and the thio­cyanate S atoms into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers.

【 授权许可】

CC BY