Crystal structure of bis­(4-benzoyl­pyridine-κN)bis­(methanol-κO)bis­(thio­cyanato-κN)cobalt(II)

Acta Crystallographica Section E: Crystallographic Communications

Suckert, S.¹  Nä¹  Werner, J.²  ther, C.²  Jess, I.³ 

[1] Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Str. 2, D-24118 Kiel, Germany

关键词: CRYSTAL STRUCTURE;    DISCRETE COMPLEX;    COBALT(II) THIOCYANATE;    4-BENZOYLPYRIDINE;    HYDROGEN BONDING.;   

DOI  :  10.1107/S2056989017004765

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The crystal structure of the title compound, [Co(NCS)2(C12H9NO)2(CH3OH)2], consists of cobalt(II) cations that are octa­hedrally coordinated by two N-terminal bonding thio­cyanato anions, two methanol mol­ecules and two 4-benzoyl­pyridine ligands into discrete complexes that are located on centres of inversion. These complexes are further linked by O—H⋯O hydrogen bonding between the hy­droxy H atom of the methanol ligand and the carbonyl O atom of the 4-benzoyl­pyridine ligand of a neighboring complex into layers parallel to (101). No pronounced inter­molecular inter­actions are observed between these layers.

【 授权许可】

CC BY