Synthesis of 3a,7a‐Dihydroindoles via Rhodium‐catalyzed Intermolecular Formal [3 + 2] Transannulation Reactions of Triazoles with Alkyl‐substituted Benzene Derivatives

Bulletin of the Korean Chemical Society

Woo Hyung Jeon¹  Eung Kim²  Hyunseok Kim²  Phil Ho Lee²  Sun‐²  Kooyeon Lee³ 

[1] Department of Bio‐Department of Chemistry Kangwon National University Chuncheon 24341 Republic of Korea;Health Technology Kangwon National University Chuncheon 24341 Republic of Korea

关键词: Triazole;    Rhodium;    Catalysis;    Microwave;    3a,7a‐;    Dihydroindole;   

DOI  :  10.1002/bkcs.11283

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

A synthetic method for a variety of 3a,7a‐dihydroindoles was demonstrated from Rh‐catalyzed intermolecular formal [3 + 2] transannulation reaction of 4‐aryl‐1‐sulfonyl‐1H‐1,2,3‐triazoles with alkyl‐substituted benzene derivatives under microwave irradiation.

【 授权许可】

Unknown