Solvent-free Microwave-Assisted Ortho-Alkylation of Aromatic Ketimine with Acrylic Acid Derivatives by Rh(I) Catalyst

Bulletin of the Korean chemical society

Jeong-Ae Ahn¹  Eun-Ae Jo¹  Chul-Ho Jun¹ 

关键词: ortho-alkylation;    Microwave;    Rhodium;    Homogeneous catalyst;    Ketimine;   

DOI  :  

学科分类：化学（综合）

来源: Korean Chemical Society

【 摘 要 】

Microwave(MW)-assisted ortho-alkylation of aromatic imine with acrylic acid derivatives was performed in the presence of a (PPh3)3RhCl catalyst, and corresponding ortho-alkylated ketones were obtained after hydrolysis of the resulting ketimines. This solventless MW-assisted ortho-alkylation was highly efficient compared with conventional heating, probably due to the specific MW effect.

【 授权许可】

Unknown