期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of chlorido(2-{[2-(4-chlorophenyl)hydrazin-1-ylidene-κN1](phenyl)methyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)iridium(III) tetraphenylborate | |
Ananthalakshmi, S.1  Devika, N.2  Raja, N.4  Therrien, B.5  | |
[1] de NeuchâDepartment of Chemistry, BIT Campus, Anna University, Tiruchirappalli 620 024, Tamil Nadu State, India;Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620 019, Tamil Nadu State, India;Institut de Chimie, Universitétel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland | |
关键词: CRYSTAL STRUCTURE; HYDRAZINYLIDENEPYRIDINE LIGAND; IRIDIUM(III) COMPLEX; PENTAMETHYLCYCLOPENTADIENYL; INTRAMOLECULAR C-H...CL HYDROGEN BOND; C-CL...[PI] INTERACTIONS; C-H...[PI] INTERACTIONS; | |
DOI : 10.1107/S2056989015003023 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The title compound, [Ir(η5-C5Me5)Cl(C18H14ClN3)]B(C6H5)4, is chiral at the metal center and crystallizes as a racemate. In the cation, the hydrazinylidenepyridine ligand is N,N-coordinated through the N-pyridyl and N-hydrazinylidene groups forming a five-membered metallacycle. An intramolecular C—H⋯Cl hydrogen bond is observed. In the crystal, centrosymmetrically-related cations are connected by C—Cl⋯π interactions, forming a dimeric structure. The crystal packing is further stabilized by weak interionic C—H⋯π interactions.
【 授权许可】
CC BY
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
RO201904034374203ZK.pdf | 424KB | download |