期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of bis(η2-ethylene)(η5-pentamethylcyclopentadienyl)cobalt | |
Ramful, C.D.1  Ylijoki, K.E.O.1  Robertson, K.N.1  | |
[1] Department of Chemistry, Saint Mary's University, 923 Robie St., Halifax, NS, B3H 3C3, Canada | |
关键词: CRYSTAL STRUCTURE; PENTAMETHYLCYCLOPENTADIENYL; OLEFIN COMPLEX; COBALT; | |
DOI : 10.1107/S2056989016012822 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The title compound, [Co(C10H15)(C2H4)2], was prepared by Na/Hg reduction of [Co2(C10H15)2(μ-Cl)2] in THF under an ethylene atmosphere and crystallized from pentane at 193 K. The Co—C(olefin) bonds have an average length of 2.022 (2) Å, while the Co—C(pentadienyl) bonds average 2.103 (19) Å. The olefin C=C bonds are 1.410 (1) Å. The dihedral angle between the planes defined by the cyclopentadienyl ligand and the two olefin ligands is 0.25 (12)°. In the crystal, molecules are linked into chains by C—H⋯π interactions.
【 授权许可】
CC BY
【 预 览 】
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