期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride | |
Ananthalakshmi, S.1  Devika, N.2  Raja, N.4  Therrien, B.5  | |
[1] de NeuchâDepartment of Chemistry, BIT Campus, Anna University, Tiruchirappalli 620 024, Tamil Nadu State, India;Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620 019, Tamil Nadu State, India;Institut de Chimie, Universitétel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland | |
关键词: CRYSTAL STRUCTURE; RHODIUM(III) COMPLEX; PENTAMETHYLCYCLOPENTADIENYL; PIANO-STOOL GEOMETRY; N-H...CL HYDROGEN BOND; | |
DOI : 10.1107/S205698901500184X | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The cation of the title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinylidenepyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chlorophenyl)hydrazin-1-ylidene]ethyl group. In the crystal, a weak interionic N—H⋯Cl hydrogen bond is observed.
【 授权许可】
CC BY
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