Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η5-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride

Acta Crystallographica Section E: Crystallographic Communications

Ananthalakshmi, S.¹  Devika, N.²  Raja, N.⁴  Therrien, B.⁵ 

[1] de NeuchâDepartment of Chemistry, BIT Campus, Anna University, Tiruchirappalli 620 024, Tamil Nadu State, India;Department of Chemistry, Urumu Dhanalakshmi College, Tiruchirappalli 620 019, Tamil Nadu State, India;Institut de Chimie, Universitétel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland

关键词: CRYSTAL STRUCTURE;    RHODIUM(III) COMPLEX;    PENTAMETHYLCYCLOPENTADIENYL;    PIANO-STOOL GEOMETRY;    N-H...CL HYDROGEN BOND;   

DOI  :  10.1107/S205698901500184X

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The cation of the title compound, [Rh(η5-C5Me5)Cl(C13H12ClN3)]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chloro­phen­yl)hydrazin-1-yl­idene]ethyl group. In the crystal, a weak inter­ionic N—H⋯Cl hydrogen bond is observed.

【 授权许可】

CC BY