Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexa­hydro-1H-cyclo­penta[b]quinolin-4-ium chloride

Acta Crystallographica Section E: Crystallographic Communications

Sridhar, G.¹  Easwaramoorthy, D.¹  Bilal, I.M.¹  Rani, S.K.¹  Solomon, K.A.² 

[1] Department of Chemistry, B.S. Abdur Rahman University, Chennai 600 048, India;Department of Chemistry, Sri Sathya Sai Center for Human Excellence, Karnataka 562 101, India

关键词: CRYSTAL STRUCTURE;    QUINOLINE;    N-H...CL HYDROGEN BONDS;   

DOI  :  10.1107/S2056989015011858

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title mol­ecular salt, C15H22N+·Cl−, arose as an unexpected product of the reaction between aniline and melanol in the presence of HCl. The central heterocyclic ring has a half-chair conformation and the five-membered ring has an envelope conformation, with the C atom linked to the N atom as the flap. In the crystal, the ions are linked by N—H⋯Cl hydrogen bonds, generating chains propagating in the [100] direction. The crystal studied was a merohedral twin with a 0.64 (3):0.36 (3) domain ratio.

【 授权许可】

CC BY