期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of 3,9,9-trimethyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinolin-4-ium chloride | |
Sridhar, G.1  Easwaramoorthy, D.1  Bilal, I.M.1  Rani, S.K.1  Solomon, K.A.2  | |
[1] Department of Chemistry, B.S. Abdur Rahman University, Chennai 600 048, India;Department of Chemistry, Sri Sathya Sai Center for Human Excellence, Karnataka 562 101, India | |
关键词: CRYSTAL STRUCTURE; QUINOLINE; N-H...CL HYDROGEN BONDS; | |
DOI : 10.1107/S2056989015011858 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The title molecular salt, C15H22N+·Cl−, arose as an unexpected product of the reaction between aniline and melanol in the presence of HCl. The central heterocyclic ring has a half-chair conformation and the five-membered ring has an envelope conformation, with the C atom linked to the N atom as the flap. In the crystal, the ions are linked by N—H⋯Cl hydrogen bonds, generating chains propagating in the [100] direction. The crystal studied was a merohedral twin with a 0.64 (3):0.36 (3) domain ratio.
【 授权许可】
CC BY
【 预 览 】
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