Crystal structure of [3-amino-2-(phenyl­diazenyl)­pyridine]chlorido­(η6-p-cymene)­ruthenium(II) chloride

Acta Crystallographica Section E: Crystallographic Communications

Romin, T.¹  Sansook, S.¹  Pakawatchai, C.¹  Hansongnern, K.¹  Nimthong Roldan, A.² 

[1] Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;Department of Chemistry, Youngstown State University, 1 University Plaza, 44555, Youngstown, OH, USA

关键词: CRYSTAL STRUCTURE;    3-AMINO-2-(PHENYLAZO)PYRIDINE;    RUTHENIUM COMPLEX;    N-H...CL HYDROGEN BONDS;   

DOI  :  10.1107/S2056989015017466

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [RuCl(C10H14)(C11H10N4)]Cl is an RuII complex in which an η6-p-cymene ligand, two N atoms of 3-amino-2-(phenyl­azo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78 (5) and 0.22 (5).

【 授权许可】

CC BY