期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of [3-amino-2-(phenyldiazenyl)pyridine]chlorido(η6-p-cymene)ruthenium(II) chloride | |
Romin, T.1  Sansook, S.1  Pakawatchai, C.1  Hansongnern, K.1  Nimthong Roldan, A.2  | |
[1] Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand;Department of Chemistry, Youngstown State University, 1 University Plaza, 44555, Youngstown, OH, USA | |
关键词: CRYSTAL STRUCTURE; 3-AMINO-2-(PHENYLAZO)PYRIDINE; RUTHENIUM COMPLEX; N-H...CL HYDROGEN BONDS; | |
DOI : 10.1107/S2056989015017466 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The title compound, [RuCl(C10H14)(C11H10N4)]Cl is an RuII complex in which an η6-p-cymene ligand, two N atoms of 3-amino-2-(phenylazo)pyridine and one Cl ion form a piano-stool coordination environment around the metal ion. In the crystal structure, N—H⋯Cl hydrogen bonds play an important role in the formation of the supramolecular zigzag chain along the a-axis direction. Disorder is observed for the isopropyl group with site-occupancy factors refined to 0.78 (5) and 0.22 (5).
【 授权许可】
CC BY
【 预 览 】
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