Crystal structure of (μ-4-hy­droxy­benzene­thiol­ato-κ2S:S)bis­(μ-phenyl­methane­thiol­ato-κ2S:S)bis­[(η6-1-isopropyl-4-methyl­benzene)­ruthenium(II)] tetra­fluorido­borate

Acta Crystallographica Section E: Crystallographic Communications

bal, D.¹  Stí²  Therrien, B.²  Sü³  ss-Fink, G.⁴ 

[1] de NeuchâInstitut de Chimie, Universitétel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland

关键词: CRYSTAL STRUCTURE;    RUTHENIUM COMPLEX;    PIANO-STOOL COORDINATION GEOMETRY;    THIOLATE LIGANDS;   

DOI  :  10.1107/S2056989015016953

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two RuII atoms to be bridged by two benzyl­thio­pheno­late units and one 4-hy­droxy­thio­pheno­late unit, with the remaining three coordination sites of each RuII atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4− counter-anion is surrounded by four cationic dinuclear complexes, showing an O—H⋯F hydrogen bond and several weak C—H⋯F inter­actions. This is the first example of an X-ray analysis of a mixed dinuclear tri­thiol­ate arene ruthenium(II) complex.

【 授权许可】

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