Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of (μ-4-hydroxybenzenethiolato-κ2S:S)bis(μ-phenylmethanethiolato-κ2S:S)bis[(η6-1-isopropyl-4-methylbenzene)ruthenium(II)] tetrafluoridoborate | |
bal, D.1  Stí2  Therrien, B.2  Sü3  ss-Fink, G.4  | |
[1] de NeuchâInstitut de Chimie, Universitétel, Avenue de Bellevaux 51, CH-2000 Neuchâtel, Switzerland | |
关键词: CRYSTAL STRUCTURE; RUTHENIUM COMPLEX; PIANO-STOOL COORDINATION GEOMETRY; THIOLATE LIGANDS; | |
DOI : 10.1107/S2056989015016953 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The crystal structure of the dinuclear arene ruthenium title complex, [Ru2(C6H5OS)(C7H7S)2(C10H14)2]BF4, shows the two RuII atoms to be bridged by two benzylthiophenolate units and one 4-hydroxythiophenolate unit, with the remaining three coordination sites of each RuII atom being occupied by p-cymene ligands, completing the typical piano-stool coordination geometry. The BF4− counter-anion is surrounded by four cationic dinuclear complexes, showing an O—H⋯F hydrogen bond and several weak C—H⋯F interactions. This is the first example of an X-ray analysis of a mixed dinuclear trithiolate arene ruthenium(II) complex.
【 授权许可】
CC BY
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