期刊论文详细信息
Acta Crystallographica Section E: Crystallographic Communications
Crystal structure of aquadioxido(2-{[(2-oxido­ethyl)­imino]­meth­yl}phenol­ato-κ3O,N,O′)molybdenum(VI)
Selvam, P.1  Parimala, S.1 
[1] National Centre for Catalysis Research and Department of Chemistry, Indian Institute of Technology-Madras, Chennai 600 036, India
关键词: CRYSTAL STRUCTURE;    DIOXIDOMOLYBDENUM(VI) COMPLEX;    HYDROGEN BONDING;   
DOI  :  10.1107/S2056989015001231
学科分类:数学(综合)
来源: International Union of Crystallography
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【 摘 要 】

The mononuclear title complex, [Mo(C9H9NO2)O2(H2O)], contains an Mo(VI) atom in a distorted octa­hedral coordination sphere defined by an Mo=O and an Mo—(OH2) bond to the axial ligands and two Mo—O bonds to phenolate and alcoholate O atoms, another Mo=O bond and one Mo—N bond to the imino N atom in the equatorial plane. The five-membered metalla-ring shows an envelope conformation. In the crystal, individual mol­ecules are connected into a layered arrangement parallel to (100) by means of O—H⋯O hydrogen bonds involving the water mol­ecule as a donor group and the O atoms of neighbouring complexes as acceptor atoms. These inter­actions lead to the formation of a three-dimensional network.

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