Acta Crystallographica Section E: Crystallographic Communications | |
Crystal structure of aquadioxido(2-{[(2-oxidoethyl)imino]methyl}phenolato-κ3O,N,O′)molybdenum(VI) | |
Selvam, P.1  Parimala, S.1  | |
[1] National Centre for Catalysis Research and Department of Chemistry, Indian Institute of Technology-Madras, Chennai 600 036, India | |
关键词: CRYSTAL STRUCTURE; DIOXIDOMOLYBDENUM(VI) COMPLEX; HYDROGEN BONDING; | |
DOI : 10.1107/S2056989015001231 | |
学科分类:数学(综合) | |
来源: International Union of Crystallography | |
【 摘 要 】
The mononuclear title complex, [Mo(C9H9NO2)O2(H2O)], contains an Mo(VI) atom in a distorted octahedral coordination sphere defined by an Mo=O and an Mo—(OH2) bond to the axial ligands and two Mo—O bonds to phenolate and alcoholate O atoms, another Mo=O bond and one Mo—N bond to the imino N atom in the equatorial plane. The five-membered metalla-ring shows an envelope conformation. In the crystal, individual molecules are connected into a layered arrangement parallel to (100) by means of O—H⋯O hydrogen bonds involving the water molecule as a donor group and the O atoms of neighbouring complexes as acceptor atoms. These interactions lead to the formation of a three-dimensional network.
【 授权许可】
CC BY
【 预 览 】
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