Crystal structure of catena-poly[N,N,N′,N′-tetra­methyl­guanidinium [(chlorido­cadmate)-di-μ-chlorido]]

Acta Crystallographica Section E: Crystallographic Communications

Maris, T.¹  Diop, L.²  Samb, A.³  Ndiaye, M.³ 

[1] Département de Chimie, Université de Montréal, 2900 Boulevard Édouard-Montpetit, Montréal, Québec, H3C 3J7, Canada;Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal;Laboratoire des Produits Naturels, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal

关键词: CRYSTAL STRUCTURE;    FIVE-COORDINATED CADMIUM;    N-H...CL HYDROGEN BONDS;    POLYANIONIC CHAIN;   

DOI  :  10.1107/S2056989015020836

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the structure of the title salt, {(C5H14N3)[CdCl3]}n, the CdII atom of the complex anion is five-coordinated by one terminal and four bridging Cl atoms. The corresponding coordination polyhedron is a distorted trigonal bipyramid, with Cd—Cl distances in the range 2.4829 (4)–2.6402 (4) Å. The bipyramids are condensed into a polyanionic zigzag chain extending parallel to [101]. The tetra­methyl­guanidinium cations are situated between the polyanionic chains and are linked to them through N—H⋯Cl hydrogen bonds, forming a layered network parallel to (010).

【 授权许可】

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