Crystal structure of di­chlorido­{4-[(E)-(meth­oxy­imino-κN)meth­yl]-1,3-thia­zol-2-amine-κN3}palladium(II)

Acta Crystallographica Section E: Crystallographic Communications

Orysyk, S.I.¹  Zholob, O.O.²  Dyakonenko, V.V.³  Pekhnyo, V.I.⁴ 

[1] , National Academy of Science of Ukraine, 60 Lenina ave., Kharkiv 61001, Ukraine;Institution Institute for Single Crystals"State Scientific "V.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, Ukraine

关键词: CRYSTAL STRUCTURE;    PALLADIUM;    MULTI-FUNCTIONAL LIGAND;    4-[(METHOXYIMINO)METHYL]-1,3-THIAZOL-2-AMINE (MIMTA);   

DOI  :  10.1107/S2056989014026619

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

In the title compound, [PdCl2(C5H7N3OS)], the PdII atom adopts a distorted square-planar coordination sphere defined by two N atoms of the bidentate ligand and two Cl atoms. The mean deviation from the coordination plane is 0.029 Å. The methyl group is not coplanar with the plane of the metallacycle [torsion angle C—O—N—C = 20.2 (4)°]. Steric repulsion between the methyl group and atoms of the metallacycle is manifested by shortened intra­molecular H⋯C contacts of 2.27, 2.38 and 2.64 Å, as compared with the sum of the van der Waals radii of 2.87 Å. The amino group participates via one H atom in the formation of an intra­molecular N—H⋯Cl hydrogen bond. In the crystal, the other H atom of the amino group links mol­ecules via bifurcated N—H⋯(Cl,O) hydrogen bonds into chains parallel to [001].

【 授权许可】

CC BY