Crystal structure of (piperidine-1-carbo­di­thio­ato-κ2S,S)[2-(pyridin-2-yl)phenyl-κ2C1,N]palladium(II)

Acta Crystallographica Section E: Crystallographic Communications

Gritcenko, R.¹  Wendt, O.F.¹  Fleckhaus, A.¹  Kondrashov, M.¹ 

[1] Centre for Analysis and Synthesis, Department of Chemistry, Lund University, PO Box 124, S-221 00 Lund, Sweden

关键词: CRYSTAL STRUCTURE;    PALLADIUM;    PHENYLPYRIDINE;    DITHIOCARBAMATE;   

DOI  :  10.1107/S2056989015015005

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol­ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the PdII atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C—Pd—N angles are all around 81° and the S—Pd—S angles are around 75°. Mol­ecules pack via dispersion inter­actions.

【 授权许可】

CC BY