Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate

Acta Crystallographica Section E: Crystallographic Communications

Lasri, J.³  Eltayeb, N.E.³  Haukka, M.⁴  Babgi, B.A.⁵ 

[1] , Department of Chemistry, University of Jyvä, PO Box 35, FI-40014, Finland;Department of Chemistry, Rabigh College of Science and Arts, PO Box 344, King Abdulaziz University, Jeddah, Saudi Arabia;University of Jyväskylä

关键词: CRYSTAL STRUCTURE;    PALLADIUM;    NITRILE;    NITRONE;    CYCLOADDITION;    N-O BOND CLEAVAGE;   

DOI  :  10.1107/S2056989017003929

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title complex, [PdCl2(C8H14N2O)2]·2H2O, was obtained by N–O bond cleavage of the oxa­diazo­line rings of the trans-[di­chlorido-bis­(2,5,5-trimethyl-5,6,7,7a-tetra­hydro­pyrrolo­[1,2-b][1,2,4]oxa­diazole-N1)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two trans-arranged chloride anions and a nitro­gen atom from each of the two neutral organic ligands. In the crystal, N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds link complex mol­ecules into double layers parallel to the bc plane.

【 授权许可】

CC BY