Crystal structure of (Z)-N-benzyl­idene-1-phenyl­methanamine oxide hydrogen peroxide monosolvate

Acta Crystallographica Section E: Crystallographic Communications

Prikhodchenko, P.V.¹  Medvedev, A.G.¹  Churakov, A.V.¹  Mikhaylov, A.A.¹ 

[1] Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii prospekt 31, Moscow 119991, Russian Federation

关键词: CRYSTAL STRUCTURE;    PEROXOSOLVATE;    N-OXIDE;    NITRONE;    HYDROGEN-BOND MOTIF;   

DOI  :  10.1107/S2056989017014499

学科分类：数学（综合）

来源: International Union of Crystallography

【 摘 要 】

The title adduct, C14H13NO·H2O2, consists of (Z)-N-benzyl­idene-1-phenyl­methanamine oxide and hydrogen peroxide mol­ecules in a 1:1 ratio. The organic coformer adopts a skew geometry with an inter-aryl-ring dihedral angle of 81.9 (2)°. In the crystal, the organic and peroxide mol­ecules are linked through both peroxide O—H donor groups to oxide O-atom acceptors, giving one-dimensional chains extending along the b axis. Present also are weak inter­molecular C—H⋯O hydrogen-bonding inter­actions.

【 授权许可】

CC BY