Curcumin-beta-cyclodextrin inclusion complex: Stability, solubility, characterisation by FT-IR, FT-Raman, X-ray diffraction and photoacoustic spectroscopy, and food application

卷:153

Mangolim, Camila Sampaio ; Moriwaki, Cristiane ; Nogueira, Ana Claudia ; Sato, Francielle ; Baesso, Mauro Luciano ; Neto, Antonio Medina ; Matioli, Graciette

State Univ Maringa UEM

关键词: Curcumin;    Cyclodextrin;    Natural colourant;    Molecular inclusion;    Spectroscopic techniques;    Co-precipitation;   

DOI  :  10.1016/j.foodchem.2013.12.067

学科分类：食品科学和技术

【 摘 要 】

Curcumin was complexed with beta-CD using co-precipitation, freeze-drying and solvent evaporation methods. Co-precipitation enabled complex formation, as indicated by the FT-IR and FT-Raman techniques via the shifts in the peaks that were assigned to the aromatic rings of curcumin. In addition, photoacoustic spectroscopy and X-ray diffraction, with the disappearance of the band related to aromatic rings, by Gaussian fitting, and modifications in the spectral lines, respectively, also suggested complex formation. The possible complexation had an efficiency of 74% and increased the solubility of the pure colourant 31-fold. Curcumin-beta-CD complex exhibited a sunlight stability 18% higher than the pure colourant. This material was stable to pH variations and storage at -15 and 4 degrees C. With an isothermal heating at 100 and 150 degrees C for 2 h, the material exhibited a colour retention of approximately 99%. The application of curcumin-beta-CD complex in vanilla ice creams intensified the colour of the products and produced a great sensorial acceptance. (C) 2013 Elsevier Ltd. All rights reserved.