Core/shell nanocomposite for biomedicine and environmental safety

2017 Global Conference on Polymer and Composite Materials

材料科学;化学

Gorban, O.^1 ; Danilenko, I.^1 ; Mitina, N.^2 ; Gorban, S.^1 ; Zaichenko, A.^2 ; Konstantinova, T.^1

Department of Materials Science and Engineering, Donetsk Institute for Physics and Engineering NAS of Ukraine, Nauki av., 46, Kyiv, Ukraine^1

Lviv Polytechnic National University, S. Bandera St. 12, Lviv, Ukraine^2

关键词: Core/shell;    Environmental safety;    ESR spectroscopy;    Inorganic complexes;    Paramagnetic nature;    Shell formation;    Synthesis route;   

Others  :  https://iopscience.iop.org/article/10.1088/1757-899X/213/1/012017/pdf
DOI  :  10.1088/1757-899X/213/1/012017

学科分类：材料科学（综合）

来源: IOP

【 摘 要 】

The two different routes for creation Cu(II) modified zirconia were seen. FTIR and ESR spectroscopy were investigated the influence of synthesis route on features of formation of such structure. It is shown that for both cases the interaction between copper (II) and Zr-OH and Zr=O is occurred and these centres have paramagnetic nature. When the Cu-contained polymer is used for shell formation, only one kind of paramagnetic centres of copper (II) is formed, but when the Cu-contained inorganic complex is used for shell formation two kinds of copper (II) paramagnetic centres are formed.