Synthesis and Characterization of Amphiphilic Iron-Sulfur Core Dendrimers

Dendrimer;Encapsulation;Structure-Property Relationships;Iron-Sulfur Cluster

Dembowa, Aneta ; Daniel L. Feldheim, Committee Member,Edmond F. Bowden, Committee Member,Christopher B. Gorman, Committee Chair,Dembowa, Aneta ; Daniel L. Feldheim ; Committee Member ; Edmond F. Bowden ; Committee Member ; Christopher B. Gorman ; Committee Chair

University:North Carolina State University

关键词: Dendrimer;    Encapsulation;    Structure-Property Relationships;    Iron-Sulfur Cluster;   

Others  :  https://repository.lib.ncsu.edu/bitstream/handle/1840.16/2249/etd.pdf?sequence=1&isAllowed=y

美国|英语

来源: null

【 摘 要 】

Synthesis of water soluble carboxylate-terminated Fe4S4-core was carried out. Convergent methodwas chosento build three generations of dendrons. Several synthetic schemes were explored. The syntheses were conducted with 4,4-bis(hydroxyphenyl)penthanol as a repeat unit andN,N-dimethyl thiocarbamate and methyl ester or methoxy-methyl as protecting groups. The conditions for deprotection and ligand exchange have been proposed. 1H, 13C and MALDI-MS were used to characterize synthesized molecules.