New Tools for CO2 Fixation by Homogeneous Catalysis - Final Technical Report

Jessop, Phillip G.

The Regents of the University of California, Davis

关键词: Carbon Dioxide Fixation;    37 Inorganic, Organic, Physical And Analytical Chemistry;    Homogeneous Catalysis;    54 Environmental Sciences;    Catalysts;   

DOI  :  10.2172/899864
RP-ID  :  DE-FG02-99ER14986 - 1
RP-ID  :  FG02-99ER14986
RP-ID  :  899864

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来源: UNT Digital Library

【 摘 要 】

The overall goal is the development of new or more efficient methods for the conversion of CO{sub 2} into useful organic products, via the design or discovery of new catalysts, ligands, solvents, and methods. Specific objectives for this funded period: (1) To develop a high-throughput screening technique and use it to develop an efficient catalyst/reagent/solvent system for the synthesis of ureas or carboxylic acids. (2) To use in-situ spectroscopic and kinetic methods to study the mechanism of the synthesis of ureas or carboxylic acids. (3) To develop bifunctional ligands capable of secondary interactions with CO{sub 2}, to detect the interactions, and to demonstrate applications to catalysis.