Chemical Depth Profiling from Neutron Reflectometry

Aktosun, Tuncay

Mississippi State University

关键词: 36 Materials Science;    Reflection;    Reflectivity;    Neutron Reflectometry;    Incidence Angle;   

DOI  :  10.2172/877659
RP-ID  :  DOE/ER/45951-12
RP-ID  :  FG02-01ER45951
RP-ID  :  877659

美国|英语

来源: UNT Digital Library

【 摘 要 】

The material profile of a thin film can be analyzed by placing the film on a substrate and by sending a neutron beam onto it at various angles of incidence. Technically, the scattering length density of the film needs to be determined as a function of depth. A reflectometer is used to measure the amount of reflection (reflectivity) as a function of the angle of incidence. Mathematically, this is equivalent to sending the neutron beam onto the film at every energy but at a fixed angle of incidence. The film profile needs to be recovered from the measured reflectivity data. Unfortunately, the unique recovery is impossible, and many distinct unrelated profiles may correspond to the same reflectivity data. In our DOE/EPSCoR sponsored research, we have developed an analytical method to uniquely recover the profile of a thin film from the measured reflectivity data. We have shown that by taking reflectivity measurements with two different substrates, one can uniquely determine the film profile. Previously, it was known that one could uniquely recover the profile by taking reflectivity measurements with three different substrates, and our findings indicate that the same goal can be accomplished by using fewer measurements. At Mississippi State University we started an informal weekly seminar (called ''the reflectometry meeting'') at to attract various undergraduate and graduate students into the field. There were about 3 undergraduate students, 6 graduate students, and 2 faculty members attending these seminars. The PI has collaborated with Dr. Norm Berk at National Institute of Standards and Technology (NIST) on various aspects of neutron reflectometry, from which various interesting problems of theoretical and practical importance have arisen. One of these problems is closely related to the important mathematical problem known as analytic extrapolation. Under appropriate conditions (known to hold in neutron reflectometry), the reflection data taken in a finite interval of neutron energies uniquely determines the data at all energies. Even though the uniqueness is assured mathematically, there are currently no available methods for analytic extrapolation. Currently, we are working on this problem as it arises in neutron reflectometry and looking for mathematical and numerical methods to extrapolate reflection data to higher and lower neutron energies. A solution to this problem is expected to have a big impact not only in neutron reflectometry, but in many areas of physics and engineering. The PI has collaborated with Prof. Paul Sacks of Iowa State University, Prof. Daniil Sarkissian of Mississippi State University, and Prof. Levon Babadzanjanz of St. Petersburg State University, Russia on mathematical and numerical aspects of neutron reflectometry. These researchers jointly worked with the PI towards the preparation of numerical routines to extract the film profile from the reflection data. We have prepared a Mathematica interface running Fortran 95 algorithms to produce reflection data from a given profile. These Fortran 95 algorithms have been prepared by updating and modifying Prof. Sacks' Fortran 77 routine and by updating Dr. Gian Felcher's (of Argonne National Laboratory) Fortran 77 routine. We are also preparing similar algorithms written in Mathematica so that they can be used without needing Fortran. We are also working towards preparing algorithms in Fortran 95 and in Mathematica to produce the film profile from the given sets of reflectivity data.