科技报告详细信息
Radiation-Induced Decomposition of U(VI) Phase to Nanocrystals of UO2 | |
Utsunomiya, S. ; Ewing, R.C. ; Wang, L. | |
United States. Department of Energy. Yucca Mountain Project Office. | |
关键词: Fission; Uraninites; Actinides; Atoms; Radiations; | |
DOI : 10.2172/859061 RP-ID : NA RP-ID : NA RP-ID : 859061 |
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美国|英语 | |
来源: UNT Digital Library | |
【 摘 要 】
U{sup 6+}-phases are common alteration products, under oxidizing conditions, of uraninite and the UO{sub 2} in spent nuclear fuel. These U{sup 6+}-phases are subjected to a radiation field caused by the {alpha}-decay of U, or in the case of spent nuclear fuel, incorporated actinides, such as {sup 239}Pu and {sup 237}Np. In order to evaluate the effects of {alpha}-decay events on the stability of the U{sup 6+}-phases, we report, for the first time, the results of ion beam irradiations (1.0 MeV Kr{sup 2+}) of U{sup 6+}-phases. The heavy-particle irradiations are used to simulate the ballistic interactions of the recoil-nucleus of an {alpha}-decay event with the surrounding structure. The Kr{sup 2+}-irradiation decomposed the U{sup 6+}-phases to UO{sub 2} nanocrystals at doses as low as 0.006 displacements per atom (dpa). U{sup 6+}-phases accumulate substantial radiation doses ({approx}1.0 displacement per atom) within 100,000 years if the concentration of incorporated {sup 239}Pu is as high as 1 wt%. Similar nanocrystals of UO{sub 2} were observed in samples from the natural fission reactors at Oklo, Gabon. Multiple cycles of radiation-induced decomposition to UO{sub 2} followed by alteration to U{sup 6+}-phases provide a mechanism for the remobilization of incorporated radionuclides.【 预 览 】
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