Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

Roark, Shane E. ; Sammells, Anthony F. ; Mackay, Richard ; Schesnack, Stewart R. ; Morrison, Scott R. ; Barton, Thomas F. ; Rolfe, Sara L. ; Balachandran, U. ; Kleiner, Richard N. ; Stephan, James E. ; Anderson, Frank E. ; Wagner, Aaron L. ; Wagner, Jon P.

Eltron Research, Inc.

关键词: 08 Hydrogen;    Coal Gasification;    Alloys;    Dissociation;    Transport;   

DOI  :  10.2172/829543
RP-ID  :  NONE
RP-ID  :  FC26-00NT40762
RP-ID  :  829543

美国|英语

来源: UNT Digital Library

【 摘 要 】

Eltron Research Inc. and team members CoorsTek, Sued Chemie, Argonne National Laboratory, and NORAM are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This project was motivated by the National Energy Technology Laboratory (NETL) Vision 21 initiative, which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. Over the past 12 months, this project has focused on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites containing hydrogen permeable alloys. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. The ceramic/ceramic composites demonstrate the lowest hydrogen permeation rates, with a maximum of approximately 0.1 mL/min/cm{sup 2} for 0.5-mm thick membranes at 800 to 950 C. Under equivalent conditions, cermets achieve a hydrogen permeation rate near 1 mL/min/cm{sup 2}, and the metal phase also improves structural stability and surface catalysis for hydrogen dissociation. Furthermore, if metals with high hydrogen permeability are used in cermets, permeation rates near 4 mL/min/cm{sup 2} are achievable with relatively thick membranes. Layered composite membranes have by far the highest permeation rates with a maximum flux in excess of 200 mL {center_dot} min{sup -1} {center_dot} cm{sup -2}. Moreover, these permeation rates were achieved at a total pressure differential across the membrane of 450 psi. Based on these results, effort during the next year will focus on this category of membranes. This report contains long-term hydrogen permeation data over eight-months of continuous operation, and permeation results as a function of operating conditions at high pressure for layered composite membranes. Additional progress with cermet and thin film membranes also is presented.