Advanced Hydrogen Transport Membranes for Vision 21 Fossil Fuel Plants

Roark, Shane E. ; Sammells, Anthony F. ; Mackay, Richard ; Morrison, Scott R. ; Rolfe, Sara L. ; Balachandran, U. ; Kleiner, Richard N. ; Stephen, James E. ; Anderson, Frank E. ; Ratnasamy, Shandra ; Wagner, Jon P. ; Brereton, Clive

Eltron Research, Inc.

关键词: 08 Hydrogen;    Coal Gasification;    Alloys;    Membranes;    01 Coal, Lignite, And Peat;   

DOI  :  10.2172/822138
RP-ID  :  NONE
RP-ID  :  FC26-00NT40762
RP-ID  :  822138

美国|英语

来源: UNT Digital Library

【 摘 要 】

The objective of this project is to develop an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. Currently, this project is focusing on four basic categories of dense membranes: (1) mixed conducting ceramic/ceramic composites, (2) mixed conducting ceramic/metal (cermet) composites, (3) cermets with hydrogen permeable metals, and (4) layered composites with hydrogen permeable alloys. The primary technical challenge in achieving the goals of this project will be to optimize membrane composition to enable practical hydrogen separation rates and chemical stability. Other key aspects of this developing technology include catalysis, ceramic processing methods, and separation unit design operating under high pressure. To achieve these technical goals, Eltron Research Inc. has organized a consortium consisting of CoorsTek, Sued Chemie, Inc. (SCI), Argonne National Laboratory (ANL), and NORAM. Hydrogen permeation rates in excess of 50 mL {center_dot} min{sup -1} {center_dot} cm{sup 2} at {approx}440 C were routinely achieved under less than optimal experimental conditions using a range of membrane compositions. Factors that limit the maximum permeation attainable were determined to be mass transport resistance of H{sub 2} to and from the membrane surface, as well as surface contamination. Mass transport resistance was partially overcome by increasing the feed and sweep gas flow rates to greater than five liters per minute. Under these experimental conditions, H2 permeation rates in excess of 350 mL {center_dot} min{sup -1} {center_dot} cm{sup 2} at {approx}440 C were attained. These results are presented in this report, in addition to progress with cermets, thin film fabrication, catalyst development, and H{sub 2} separation unit scale up.