Metal alkoxides: templates for organometallic chemistry and catalysis. Final technical report on DE FG 02-86ER13570

Chisholm, Malcolm H.

Indiana University, Bloomington, IN (United States)

关键词: Alkoxides;    Chemical Reactions;    Polylactide;    Polyolefins;    37 Inorganic, Organic, Physical And Analytical Chemistry;   

DOI  :  10.2172/808502
RP-ID  :  NONE
RP-ID  :  FG02-86ER13570
RP-ID  :  808502

美国|英语

来源: UNT Digital Library

【 摘 要 】

The physical properties and chemical reactivities of a series of alkoxide, fluoroalkoxide and thiolate compounds of molybdenum and tungsten having M{triple_bond}M or M{triple_bond}N bonds have been examined which reveal the influence of the pi-donor properties of the ligands: RO > R{sub f}O{approx}RS. Single-site metal alkoxide catalysts for the ring-opening polymerization of lactides have been prepared for the metals magnesium, zinc, and aluminum.