Solar Energy Research Center Instrumentation Facility

Meyer, Thomas, J. ; Papanikolas, John, P.

University of North Carolina at Chapel Hill (UNC-CH)

关键词: Solar Energy;    Fuel Cell;    Nanomaterials;    Device;    Laser;   

DOI  :  10.2172/1029115
RP-ID  :  DOE/EE0003188-1
RP-ID  :  EE0003188
RP-ID  :  1029115

美国|英语

来源: UNT Digital Library

【 摘 要 】

SOLAR ENERGY RESEARCH CENTER INSTRUMENTATION FACILITY The mission of the Solar Energy Research Center (UNC SERC) at the University of North Carolina at Chapel Hill (UNC-CH) is to establish a world leading effort in solar fuels research and to develop the materials and methods needed to fabricate the next generation of solar energy devices. We are addressing the fundamental issues that will drive new strategies for solar energy conversion and the engineering challenges that must be met in order to convert discoveries made in the laboratory into commercially available devices. The development of a photoelectrosynthesis cell (PEC) for solar fuels production faces daunting requirements: (1) Absorb a large fraction of sunlight; (2) Carry out artificial photosynthesis which involves multiple complex reaction steps; (3) Avoid competitive and deleterious side and reverse reactions; (4) Perform 13 million catalytic cycles per year with minimal degradation; (5) Use non-toxic materials; (6) Cost-effectiveness. PEC efficiency is directly determined by the kinetics of each reaction step. The UNC SERC is addressing this challenge by taking a broad interdisciplinary approach in a highly collaborative setting, drawing on expertise across a broad range of disciplines in chemistry, physics and materials science. By taking a systematic approach toward a fundamental understanding of the mechanism of each step, we will be able to gain unique insight and optimize PEC design. Access to cutting-edge spectroscopic tools is critical to this research effort. We have built professionally-staffed facilities equipped with the state-of the-art instrumentation funded by this award. The combination of staff, facilities, and instrumentation specifically tailored for solar fuels research establishes the UNC Solar Energy Research Center Instrumentation Facility as a unique, world-class capability. This congressionally directed project funded the development of two user facilities: TASK 1: SOLAR DEVICE FABRICATION LABORATORY DEVELOPMENT The space allocated for this laboratory was “shell space” that required an upfit in order to accommodate nano-fabrication equipment in a quasi-clean room environment. This construction project (cost $279,736) met the non-federal cost share requirement of $250,000 for this award. The central element of the fabrication laboratory is a new $400,000+ stand-alone system, funded by other sources, for fabricating and characterizing photovoltaic devices, in a state-of-the-art nanofabrication environment. This congressionally directed project also included the purchase of an energy dispersive x-ray analysis (EDX) detector for a pre-existing transmission electron microscope (TEM). This detector allows elemental analysis and elemental mapping of materials used to fabricate solar energy devices which is a key priority for our research center. TASK 2: SOLAR ENERGY SPECTROSCOPY LABORATORY DEVELOPMENT (INSTRUMENTATION) This laboratory provides access to modern spectroscopy and photolysis instrumentation for characterizing devices, materials and components on time scales ranging from femtoseconds to seconds and for elucidating mechanisms. The goals of this congressionally directed project included the purchase and installation of spectroscopy and photolysis instrumentation that would substantially and meaningfully enhance the capabilities of this laboratory. Some changes were made to the list of equipment proposed in the original budget. These changes did not represent a change in scope, approach or aims of this project. All of the capabilities and experiments represented in the original budget were maintained. The outcome of this Congressionally Directed Project has been the development of world-class fabrication and spectroscopy user facilities for solar fuels research at UNC-CH. This award has provided a significant augmentation of our pre-existing instrumentation capabilities which were funded by earlier UNC SERC projects, including the Energy Frontier Research Center UNC EFRC, funded by the US Department of Energy Office of Basic Energy Sciences. Equipment funded by this congressional award has provided important new capabilities for UNC SERC and has greatly facilitated collaborative research by many multi-institutional teams in the six partner institutions of the UNC EFRC, including Duke University, North Carolina Central University, and North Carolina State University. This state-of-the-art instrumentation has allowed us to design cutting-edge experiments that provide insight into the molecular structure and dynamics of materials and components for solar energy conversion under real working conditions. This research has resulted in ten publications already published or in preparation that acknowledge support from DOE EERE for this congressionally directed project.