Hierarchical Nanoceramics for Industrial Process Sensors

Ruud, James, A. ; Brosnan, Kristen, H. ; Striker, Todd ; Ramaswamy, Vidya ; Aceto, Steven, C. ; Gao, Yan ; Willson, Patrick, D. ; Manoharan, Mohan ; Armstrong, Eric, N., Wachsman, Eric, D. ; Kao, Chi-Chang

GE Global Research, Niskayuna, NY

关键词: 77 Nanoscience And Nanotechnology;    Nanostructures;    Feedback;    Surface Area;    Electrodes;   

DOI  :  10.2172/1018940
RP-ID  :  DOE/GO/16053
RP-ID  :  FG36-06GO16053
RP-ID  :  1018940

美国|英语

来源: UNT Digital Library

【 摘 要 】

This project developed a robust, tunable, hierarchical nanoceramics materials platform for industrial process sensors in harsh-environments. Control of material structure at multiple length scales from nano to macro increased the sensing response of the materials to combustion gases. These materials operated at relatively high temperatures, enabling detection close to the source of combustion. It is anticipated that these materials can form the basis for a new class of sensors enabling widespread use of efficient combustion processes with closed loop feedback control in the energy-intensive industries. The first phase of the project focused on materials selection and process development, leading to hierarchical nanoceramics that were evaluated for sensing performance. The second phase focused on optimizing the materials processes and microstructures, followed by validation of performance of a prototype sensor in a laboratory combustion environment. The objectives of this project were achieved by: (1) synthesizing and optimizing hierarchical nanostructures; (2) synthesizing and optimizing sensing nanomaterials; (3) integrating sensing functionality into hierarchical nanostructures; (4) demonstrating material performance in a sensing element; and (5) validating material performance in a simulated service environment. The project developed hierarchical nanoceramic electrodes for mixed potential zirconia gas sensors with increased surface area and demonstrated tailored electrocatalytic activity operable at high temperatures enabling detection of products of combustion such as NOx close to the source of combustion. Methods were developed for synthesis of hierarchical nanostructures with high, stable surface area, integrated catalytic functionality within the structures for gas sensing, and demonstrated materials performance in harsh lab and combustion gas environments.