Laboratory Investigations in Support of Carbon Dioxide-in-Water Emulsions Stabilized by Fine Particles for Ocean and Geologic Sequestration of Carbon Dioxide

Dan Golomb ; David Ryan ; Eugene Barry

关键词: AQUIFERS;    BINARY MIXTURES;    CARBON;    CARBON DIOXIDE;    ELECTROSTATIC PRECIPITATORS;    GEOLOGIC FORMATIONS;    HYDROGEN SULFIDES;    LIMESTONE;    MIXTURES;    PARTICLE SIZE;    POWER PLANTS;    PROGRESS REPORT;    SIDERITE;    TRAPPING;    WATER;   

DOI  :  10.2172/901202
RP-ID  :  None
PID  :  OSTI ID: 901202
Others  :  TRN: US200713%%331

美国|英语

来源: SciTech Connect

【 摘 要 】

Since the submission of our last Semi-annual Report, dated September 2006, the research objectives of this Co-operative Agreement shifted toward geologic sequestration of carbon dioxide. In the period September 2006-February 2007, experiments were conducted in a High-Pressure Batch Reactor (HPBR) for creating emulsions of liquid carbon dioxide (/CO{sub 2})-in-water stabilized by fine particles for geologic sequestration of CO{sub 2}. Also, emulsions were created in water of a binary mixture of liquid carbon dioxide and liquid hydrogen sulfide (/H{sub 2}S), called Acid Gas (AG). This leads to the possibility of safe disposal of AG in deep geologic formations, such as saline aquifers. The stabilizing particles included pulverized limestone (CaCO{sub 3}), unprocessed flyash, collected by an electrostatic precipitator at a local coal-fired power plant, and pulverized siderite (FeCO{sub 3}). Particle size ranged from submicron to a few micrometers. The first important finding is that /CO{sub 2} and /H{sub 2}S freely mix as a binary liquid without phase separation. The next finding is that the mixture of /CO{sub 2} and /H{sub 2}S can be emulsified in water using fine particles as emulsifying agents. Such emulsions are stable over prolonged periods, so it should not be a problem to inject an emulsion into subterranean formations. The advantage of injecting an emulsion into subterranean formations is that it is denser than the pure liquid, therefore it is likely to disperse in the bottom of the geologic formation, rather than buoying upward (called fingering). In such a fashion, the risk of the liquids escaping from the formation, and possibly re-emerging into the atmosphere, is minimized. This is especially important for H{sub 2}S, because it is a highly toxic gas. Furthermore, the emulsion may interact with the surrounding minerals, causing mineral trapping. This may lead to longer sequestration periods than injecting the pure liquids alone.