A simplified model of TiH1.65/KClO4 pyrotechnic ignition.

Chen, Ken Shuang

关键词: CHEMICAL REACTIONS;    HEAT TRANSFER;    IGNITION;    JOULE HEATING;    KINETICS;    REACTION KINETICS;    TRANSPORT;    VALIDATION Ignition.;    Chemical reaction;    Rate of-Mathematical models.;   

DOI  :  10.2172/959109
RP-ID  :  SAND2009-1217
PID  :  OSTI ID: 959109
Others  :  TRN: US201016%%555

学科分类：化学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

A simplified model was developed and is presented in this report for simulating thermal transport coupled with chemical reactions that lead to the pyrotechnic ignition of TiH1.65/KClO4 powder. The model takes into account Joule heating via a bridgewire, thermal contact resistance at the wire/powder interface, convective heat loss to the surroundings, and heat released from the TiH1.65- and KClO4-decomposition and TiO2-oxidation reactions. Chemical kinetic sub-models were put forth to describe the chemical reaction rate(s) and quantify the resultant heat release. The simplified model predicts pyrotechnic ignition when heat from the pyrotechnic reactions is accounted for. Effects of six key parameters on ignition were examined. It was found that the two reaction-rate parameters and the thermal contact resistance significantly affect the dynamic ignition process whereas the convective heat transfer coefficient essentially has no effect on the ignition time. Effects of the initial/ambient temperature and electrical current load through the wire are as expected. Ignition time increases as the initial/ambient temperature is lowered or the wire current load is reduced. Lastly, critical needs such as experiments to determine reaction-rate and other model-input parameters and to measure temperature profiles, time to ignition and burn-rate data for model validation as well as efforts in incorporating reaction-rate dependency on pressure are pointed out.