Normetex Pump Alternatives Study

Clark, Elliot A.

关键词: ETHYLENE PROPYLENE DIENE POLYMERS;    TRITIUM;    ETHYLENE;    PROPYLENE;    RADIOACTIVE WASTES;    OILS;    PUMPS;    COLD TRAPS;    HYDROFLUORIC ACID;    IONIZING RADIATIONS;    CHLORINE;    FLUORINE;    HYDROCHLORIC ACID;    METALS;    DESIGN;    LIQUIDS;    MONITORS;    WATER;    BY-PRODUCTS;    FILTERS;    MONOMERS;    PERFORMANCE;    PROCESSING;    SOLIDS;    STABILITY tritium facility;    pumps;    polymer;    oil;    degradation;   

DOI  :  10.2172/1082300
RP-ID  :  SRNL-STI-2013-00325
PID  :  OSTI ID: 1082300
Others  :  TRN: US1300105

美国|英语

来源: SciTech Connect

【 摘 要 】

A mainstay pump for tritium systems, the Normetex scroll pump, is currently unavailable because the Normetex company went out of business. This pump was an all-metal scroll pump that served tritium processing facilities very well. Current tritium system operators are evaluating replacement pumps for the Normetex pump and for general used in tritium service. An all-metal equivalent alternative to the Normetex pump has not yet been identified. 1. The ideal replacement tritium pump would be hermetically sealed and contain no polymer components or oils. Polymers and oils degrade over time when they contact ionizing radiation. 2. Halogenated polymers (containing fluorine, chlorine, or both) and oils are commonly found in pumps. These materials have many properties that surpass those of hydrocarbon-based polymers and oils, including thermal stability (higher operating temperature) and better chemical resistance. Unfortunately, they are less resistant to degradation from ionizing radiation than hydrocarbon-based materials (in general). 3. Polymers and oils can form gaseous, condensable (HF, TF), liquid, and solid species when exposed to ionizing radiation. For example, halogenated polymers form HF and HCl, which are extremely corrosive upon reaction with water. If a pump containing polymers or oils must be used in a tritium system, the system must be designed to be able to process the unwanted by-products. Design features to mitigate degradation products include filters and chemical or physical traps (eg. cold traps, oil traps). 4. Polymer components can work in tritium systems, but must be replaced regularly. Polymer components performance should be monitored or be regularly tested, and regular replacement of components should be viewed as an expected normal event. A radioactive waste stream must be established to dispose of used polymer components and oil with an approved disposal plan developed based on the facility location and its regulators. Polymers have varying resistances to ionizing radiation - aromatic polymers such as polyimide Vespel (TM) and the elastomer EPDM (ethylene propylene diene monomer) have been found to be more resistant to degradation in tritium than other polymers. This report presents information to help select replacement pumps for Normetex pumps in tritium systems. Several pumps being considered as Normetex replacement pumps are discussed.