Conduction Mechanisms and Structure of Ionomeric Single-Ion Conductors | |
Colby, Ralph H. ; Maranas, Janna K ; Mueller, Karl T ; Runt, James ; Winey, Karen I | |
关键词: conduction mechanisms; ionomeric single-ion conductors; | |
DOI : 10.2172/1171798 RP-ID : 46409Final PID : OSTI ID: 1171798 |
|
学科分类:材料科学(综合) | |
美国|英语 | |
来源: SciTech Connect | |
【 摘 要 】
Our team has designed using DFT (Gaussian) and synthesized low glass transition temperature single-ion conductors that are either polyanions that conduct small cations Li, Na, Cs or polycations that conduct small anions F, OH, Br. We utilize a wide range of complimentary experimental materials charactization tools to understand ion transport; differential scanning calorimetry, dielectric relaxation spectroscopy, infrared spectroscopy, nuclear magnetic resonance spectroscopy, linear viscoelasticity, X-ray scattering and molecular dynamics simulations. The glass transition temperature Tg needs to be as low as possible to facilitate ion transport, so the nonionic parts of the polymer need to be polar, flexible and have strong solvation interactions with the ions. The lowest Tg we have managed for polyanions conducting Li is -60 C. In contrast, polysiloxanes with PEO side chains and tetrabutylphosphonium cationic side groups have Tg ~ -75C that barely increases with ion content, as anticipated by DFT. A survey of all polyanions in the literature suggests that Tg < -80C is needed to achieve the 10-4 S/cm conductivity needed for battery separators.
【 预 览 】
Files | Size | Format | View |
---|---|---|---|
1413KB | download |