Nitrogen Atom Transfer From High Valent Iron Nitrides

Johnson, Michael D.¹  Smith, Jeremy M.² 

[1] New Mexico State Univ., Las Cruces, NM (United States);Indiana Univ., Bloomington, IN (United States)

关键词: iron nitrides;    catalysis;    aziridines;   

DOI  :  10.2172/1236964
RP-ID  :  DOE-NMSU--15996
PID  :  OSTI ID: 1236964

学科分类：化学（综合）

美国|英语

来源: SciTech Connect

【 摘 要 】

This report describes the synthesis and reactions of high valent iron nitrides. Organonitrogen compounds such as aziridines are useful species for organic synthesis, but there are few efficient methods for their synthesis. Using iron nitrides to catalytically access these species may allow for their synthesis in an energy-and atom-efficient manner. We have developed a new ligand framework to achieve these goals as well as providing a method for inducing previously unknown reactivity.