Nano-crystallization of amorphous alloys by ultra-rapid annealing: An effective approach to magnetic softening

JOURNAL OF ALLOYS AND COMPOUNDS

卷:735

Article

Suzuki, K.¹  Parsons, R.¹  Zang, B.¹  Onodera, K.²  Kishimoto, H.²  Shoji, T.²  Kato, A.² 

[1] Monash Univ, Dept Mat Sci & Engn, Clayton, Vic 3800, Australia

[2] Toyota Motor Co Ltd, Mishu Ku, Susono, Shizuoka 4101193, Japan

关键词: Amorphous materials;    Nanostructures;    Liquid quenching;    Magnetic measurements;   

DOI  :  10.1016/j.jallcom.2017.11.110

来源: Elsevier

【 摘 要 】

Primary crystallization of Fe-based amorphous precursors often results in the formation of magnetically soft nanostructures. The vast majority of alloys developed for this processing route contain nonmagnetic additives such as Cu and Nb for large nucleation rates and small crystal growth rates. However, we have demonstrated that magnetically soft nanostructures can be obtained in a simple Fe-B binary system without these traditional additives by employing ultra-rapid annealing. This is of technological significance as the Fe content in the nanostructure is increased to that of Si steels and a high saturation magnetization up to 1.92 T is obtained along with a low coercivity < 8 A/m. The nanoscale grain refinement in the Fe-B binary alloys is attributable to the contribution of viscous flow to the homogeneous nucleation kinetics. The formation of magnetically soft nanostructures in a simple Fe-B binary system opens up the possibility for further alloy development in compositions which were previously abandoned. (C) 2017 Published by Elsevier B.V.

【 授权许可】

Free