Unsaturated hemiwicking dynamics on surfaces with irregular roughness

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:604

Article

Varady, Mark J.¹  Mantooth, Brent A.¹ 

[1] US Army Combat Capabil Dev Command Chem Biol Ctr, 8198 Blackhawk Rd, Aberdeen Proving Ground, MD 21010 USA

关键词: Liquid spreading;    Hemiwicking;    Porous materials;    Capillary pressure;    Relative permeability;    Richards equation;    Micropillar array approximation;   

DOI  :  10.1016/j.jcis.2021.06.175

来源: Elsevier

【 摘 要 】

Hypothesis: Spreading of wetting liquids on rough surfaces can occur in a regime termed hemiwicking in which liquid advances ahead of the bulk liquid droplet front under the influence of capillary forces induced by the surface topography. When the surface topography is periodic as in the case for micropillar arrays, the wetting front is sharp and models describing the wetting dynamics can be derived directly from the periodic geometry. For materials with a highly irregular surface topography, the wetting front is diffuse and deriving analytical spreading model parameters directly from the surface topography is not generally possible. Experiments: In this work, a previously published model for liquid spreading on thin porous materials is modified to incorporate unsaturated spreading ahead of the bulk liquid droplet using Richards equation. The permeability, K, and capillary pressure, pc, of the liquid in the surface roughness are the primary model parameters describing the spreading dynamics in Richards equation. These are determined by fitting to one-dimensional spreading experiments of silicone oil on a polyurethane-based paint coating with roughness on the scale of microns. Findings: The resulting predictions of spreading dynamics for droplets with different initial sizes is good. It is also shown that reasonable model parameters can also be determined from the irregular surface topography by spatial filtering over 10 mm wavelength increments covering the range 10-500 mm. Approximate periodic micropillar arrays are defined from the filtered topography for each wavelength increment, enabling analytical estimates of the permeability and capillary pressure. Although using only the surface topography results in somewhat less accurate predictions, the savings in experimental and computational effort make it an attractive method for determining spreading model parameters. Published by Elsevier Inc.

【 授权许可】

Free