Can hydrodynamic contact line paradox be solved by evaporation-condensation?

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:460

Article

Janecek, V.¹  Doumenc, F.^1,2  Guerrier, B.¹  Nikolayev, V. S.³ 

[1] Univ Paris 11, CNRS, Lab FAST, F-91405 Orsay, France

[2] Univ Paris 06, Sorbonne Univ, UFR 919, F-75005 Paris, France

[3] CEA Saclay, DSM, IRAMIS, Serv Phys Etat Condense,CNRS,UMR 3680, F-91191 Gif Sur Yvette, France

关键词: Wetting dynamics;    Contact line motion;    Evaporation-condensation;    Kelvin effect;   

DOI  :  10.1016/j.jcis.2015.08.062

来源: Elsevier

【 摘 要 】

We investigate a possibility to regularize the hydrodynamic contact line singularity in the configuration of partial wetting (liquid wedge on a solid substrate) via evaporation condensation, when an inert gas is present in the atmosphere above the liquid. The no-slip condition is imposed at the solid liquid interface and the system is assumed to be isothermal. The mass exchange dynamics is controlled by vapor diffusion in the inert gas and interfacial kinetic resistance. The coupling between the liquid meniscus curvature and mass exchange is provided by the Kelvin effect. The atmosphere is saturated and the substrate moves at a steady velocity with respect to the liquid wedge. A multi-scale analysis is performed. The liquid dynamics description in the phase-change-controlled microregion and visco-capillary intermediate region is based on the lubrication equations. The vapor diffusion is considered in the gas phase. It is shown that from the mathematical point of view, the phase exchange relieves the contact line singularity. The liquid mass is conserved: evaporation existing on a part of the meniscus and condensation occurring over another part compensate exactly each other. However, numerical estimations carried out for three common fluids (ethanol, water and glycerol) at the ambient conditions show that the characteristic length scales are tiny. (C) 2015 Elsevier Inc. All rights reserved.

【 授权许可】

Free