Macroscopic rods from assembled colloidal particles of hydrothermally carbonized glucose and their use as templates for silicon carbide and tricopper silicide

JOURNAL OF COLLOID AND INTERFACE SCIENCE

卷:602

Article

Wang, Xia¹  Hao, Wenming^1,2  Zhang, Peng¹  Szego, Anthony E.¹  Svensson, Gunnar¹  Hedin, Niklas¹ 

[1] Stockholm Univ, Dept Mat & Environm Chem, Svante Arrhenius Vag 16 C, SE-10691 Stockholm, Sweden

[2] Taiyuan Univ Technol, Sch Chem & Chem Engn, 79 West Yingze St CN, Taiyuan 030024, Peoples R China

关键词: colloids;    assembly;    hydrothermally carbonization;    monodisperse;    templating;    reactive infiltration;    silicon carbide;    hydrochar;   

DOI  :  10.1016/j.jcis.2021.06.016

来源: Elsevier

【 摘 要 】

Self-aggregated colloids can be used for the preparation of materials, and we studied long rod-like aggregates formed on the evaporation of water from dispersed particles of colloidal hydrochar. The monodispersed hydrochar particles (100-200 nm) were synthesized by the hydrothermal carbonization of glucose and purified through dialysis. During the synthesis they formed colloidal dispersions which were electrostatically stable at intermediate to high pH and at low ion strengths. On the evaporation of water, macroscopically large rods formed from the dispersions at intermediate pH conditions. The rods formed at the solid-water interface orthogonally oriented with respect to the drying direction. Pyrolysis rendered the rods highly porous without qualitatively affecting their shape. A Cu-Si alloy was reactively infiltrated into the in-situ pyrolyzed hydrochars and composites of tricopper silicide (Cu3Si)-silicon carbide (SiC)/carbon formed. During this process, the Si atoms reacted with the C atoms, which in turned caused the alloy to wet and further react with the carbon. The shape of the underlying carbon template was maintained during the reactions, and the formed composite preparation was subsequently calcined into a Cu3Si-SiC-based replica of the rod-like assemblies of carbon-based colloidal particles. Transmission and scanning electron microscopy, and X-ray diffraction were used to study the shape, composition, and structure of the formed solids. Further studies of materials prepared with reactive infiltration of alloys into self-aggregated and carbon-based solids can be justified from a perspective of colloidal science, as well as the explorative use of hydrochar prepared from real biomass, exploration of the compositional space in relation to the reactive infiltration, and applications of the materials in catalysis. (C) 2021 The Author(s). Published by Elsevier Inc.

【 授权许可】

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