Palliative effects of H2 on SOFCs operating with carbon containing fuels

JOURNAL OF POWER SOURCES

卷:372

Article

Reeping, Kyle W.¹  Bohn, Jessie M.¹  Walker, Robert A.^1,2 

[1] Montana State Univ, Dept Chem & Biochem, Bozeman, MT 59717 USA

[2] Montana State Univ, Montana Mat Sci Program, Bozeman, MT 59717 USA

关键词: SOFC;    Chlorine;    Methane;    Biogas;    Hydrogen;    Raman;   

DOI  :  10.1016/j.jpowsour.2017.10.071

来源: Elsevier

【 摘 要 】

Chlorine can accelerate degradation of solid oxide fuel cell (SOFC) Ni-based anodes operating on carbon containing fuels through several different mechanisms. However, supplementing the fuel with a small percentage of excess molecular hydrogen effectively masks the degradation to the catalytic activity of the Ni and carbon fuel cracking reaction reactions. Experiments described in this work explore the chemistry behind the palliative effect of hydrogen on SOFCs operating with chlorine-contaminated, carbon-containing fuels using a suite of independent, complementary techniques. Operando Raman spectroscopy is used to monitor carbon accumulation and, by inference, Ni catalytic activity while electrochemical techniques including electrochemical impedance spectroscopy and voltammetry are used to monitor overall cell performance. Briefly, hydrogen not only completely hides degradation observed with chlorine-contaminated carbon-containing fuels, but also actively removes adsorbed chlorine from the surface of the Ni, allowing for the methane cracking reaction to continue, albeit at a slower rate. When hydrogen is removed from the fuel stream the cell fails immediately due to chlorine occupation of methane/biogas reaction sites.

【 授权许可】

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