Core-shell Si@TiO2 nanosphere anode by atomic layer deposition for Li-ion batteries

JOURNAL OF POWER SOURCES

卷:308

Article

Bai, Ying^1,2,5  Yan, Dong^1,2  Yu, Caiyan^1,2  Cao, Lina^3,4  Wang, Chunlei^3,4  Zhang, Jinshui⁵  Zhu, Huiyuan⁵  Hu, Yong-Sheng⁶  Dai, Sheng⁵  Lu, Junling^3,4  Zhang, Weifeng^1,2 

[1] Henan Univ, Key Lab Photovolta Mat Henan Prov, Kaifeng 475004, Peoples R China

[2] Henan Univ, Sch Phys & Elect, Kaifeng 475004, Peoples R China

[3] Univ Sci & Technol China, iChem, Hefei Natl Lab Phys Sci Microscale, Dept Chem Phys, Hefei 230026, Peoples R China

[4] Univ Sci & Technol China, CAS Key Lab Mat Energy Convers, Hefei 230026, Peoples R China

[5] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[6] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China

关键词: Silicon nanospheres;    Titanium dioxide overcoating;    Atomic layer deposition (ALD);    Cycling performance;    Buffering effect;   

DOI  :  10.1016/j.jpowsour.2016.01.049

来源: Elsevier

【 摘 要 】

Silicon (Si) has been regarded as next-generation anode for high-energy lithium-ion batteries (LIBs) due to its high Li storage capacity (4200 mA h g(-1)). However, the mechanical degradation and resultant capacity fade critically hinder its practical application. In this regard, we demonstrate that nanocoating of Si spheres with a 3 nm titanium dioxide (TiO2) layer via atomic layer deposition (ALD) can utmostly balance the high conductivity and the good structural stability to improve the cycling stability of Si core material. The resultant sample, Si@TiO2-3 nm core-shell nanospheres, exhibits the best electrochemical performance of all with a highest initial Coulombic efficiency and specific charge capacity retention after 50 cycles at 0.1C (82.39% and 1580.3 mA h g(-1)). In addition to making full advantage of the ALD technique, we believe that our strategy and comprehension in coating the electrode and the active material could provide a useful pathway towards enhancing Si anode material itself and community of LIBs. (C) 2016 Elsevier B.V. All rights reserved.

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