Durability of symmetric-structured metal-supported solid oxide fuel cells

JOURNAL OF POWER SOURCES

卷:369

Article

Tucker, Michael C.¹ 

[1] Lawrence Berkeley Natl Lab, Energy Technol Area, Energy Convers Grp, 1 Cyclotron Rd, Berkeley, CA 94720 USA

关键词: SOFC;    Metal-supported;    Chromium poisoning;    Symmetric cell;   

DOI  :  10.1016/j.jpowsour.2017.09.075

来源: Elsevier

【 摘 要 】

Symmetric-structure metal-supported solid oxide fuel cells (MS-SOFC) with YSZ electrolyte are fabricated with porous YSZ backbone electrodes, stainless steel supports, and infiltrated catalysts on both anode and cathode side. Durability towards aggressive thermal and redox cycling, and long-term operation is assessed. Many sealing material candidates are screened for compatibility with the cell materials and operating conditions, and a commercial sealing glass, GM31107, is selected. LSM/SDCN cells are then subjected to 200 very fast thermal cycles and 20 complete redox cycles, with minimal impact to cell performance. LSM/SDCN and SDCN/SDCN cells are operated for more than 1200 hat 700 degrees C. The seal and cell hermeticity is maintained, and cell ohmic impedance does not change significantly during operation. Electrode polarization increases during operation, leading to significant degradation of the cell performance. In-operando EIS and post-mortem SEM/EDS analysis suggest that catalyst coarsening and cathode Cr deposition are the dominant degradation modes. (C) 2017 Elsevier B.V. All rights reserved.

【 授权许可】

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