Structure, surface and reactivity of activated carbon: From model soot to Bio Diesel soot

FUEL

卷:257

Article

Zhang, Hailong^1,2  Li, Shanshan³  Jiao, Yi⁴  Iojoiu, Eduard Emil⁵  Da Costa, Patrick¹  Galvez, Maria Elena¹  Chen, Yaoqiang⁶ 

[1] Sorbonne Univ, CNRS, Inst Jean Le Rond dAlembert, 2 Pl Gare Ceinture, F-78210 St Cyr Lecole, France

[2] Sichuan Univ, Coll Chem Engn, Chengdu 610064, Sichuan, Peoples R China

[3] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn China, Chengdu 610065, Sichuan, Peoples R China

[4] Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610064, Sichuan, Peoples R China

[5] Renault Trucks Volvo Grp Trucks Technol, Powertrain Engn, 99 Route Lyon, F-69806 St Priest, France

[6] Sichuan Univ, Coll Chem, Chengdu 610064, Sichuan, Peoples R China

关键词: Biodiesel soot;    Nanostructure;    Soot activation;    Surface property;    Soot oxidation reactivity;   

DOI  :  10.1016/j.fuel.2019.116038

来源: Elsevier

【 摘 要 】

The present work aims to investigate and compare the structure, surface and reactivity of the activated Printex U carbon black and real Bio soot samples through BET, Raman, HRTEM, XPS, DRIFTS and temperature-programmed oxidation (TPO). TPO evidenced that the activated Printex U carbon black was more reactive than the activated Biodiesel soot B7 and B100) generated from a real engine under both O-2 and NO + O-2. BET displayed an increased surface area and a decreased pore size for the activated soot. Raman and HRTEM revealed that the activated soot showed decreased structural order. The morphology features also confirmed different combustion pathway for Printex U and B100. XPS illustrated that the activation decreased surface graphene carbon and increased surface oxygen content. DRIFTS indicated that real Bio soot had higher concentration of surface functional groups than Printex U model soot, and a more apparent increase in surface functional groups was observed for the activated Printex U soot. It was proved that the reactivity of the activated Printex U is more dependent on structural and surface properties compared with that of the activated Biodiesel soot samples.

【 授权许可】

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