期刊论文详细信息
FUEL 卷:259
Experimental investigation on sorption enhanced gasification (SEG) of biomass in a fluidized bed reactor for producing a tailored syngas
Article; Proceedings Paper
Martinez, I.1  Kulakova, V.1  Grasa, G.1  Murillo, R.1 
[1] ICB CSIC, Dept Energy & Environm, Spanish Res Council, Inst Carboquim, Miguel Luesma Castan 4, Zaragoza 50018, Spain
关键词: Steam gasification;    Bubbling fluidized bed;    Biomass;    CO2 separation;    Synthetic fuel production;   
DOI  :  10.1016/j.fuel.2019.116252
来源: Elsevier
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【 摘 要 】

Synthetic fuel production from renewable energy sources like biomass is gaining importance driven by the ambitious targets for reducing greenhouse gas emissions worldwide. Sorption enhanced gasification (SEG) proposes carrying out the gasification of biomass in the presence of a CO2 sorbent, which allows producing a syngas with a suitable composition for a subsequent synthetic fuel production step. This study aims at analysing the effect of different operating parameters (e.g. steam-to-carbon (S/C) ratio, CO2 sorption capacity and sorbent-to-biomass ratio) in the syngas composition and char conversion obtained in a 30 kW(th) bubbling fluidized bed gasifier, using grape seeds as feedstock. The importance of reducing the formation of higher hydrocarbons through a high steam-to-carbon ratio and using a CO2 sorbent with high sorption capacity is assessed. C-3-C-4 and unsaturated C-2 hydrocarbons contents below 1%vol. (in dry and N-2 free basis) can be achieved when working with S/C ratios of 1.5 at gasification temperatures from 700 to 740 degrees C. Varying the amount of the CO2 separated in the gasifier (by modifying the temperature or the CO2 sorption capacity of the sorbent) the content of H-2, CO and CO2 in the syngas produced can be greatly modified, resulting in a module M=(H-2-CO2)/(CO+CO2) that ranges from 1.2 to almost 3.

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