A green and high throughput method for salt determination in crude oil using digital image-based colorimetry in a portable device

FUEL

卷:289

Article

Holkem, Alice P.¹  Voss, Monica²  Schlesner, Sandra K.²  Helfer, Gilson A.³  Costa, Adilson B.^4,5  Barin, Juliano S.²  Mueller, Edson, I¹  Mello, Paola A.¹ 

[1] Univ Fed Santa Maria, Dept Quim, BR-97105900 Santa Maria, RS, Brazil

[2] Univ Fed Santa Maria, Dept Tecnol & Ciencia Alimentos, BR-97105900 Santa Maria, RS, Brazil

[3] Univ Santa Cruz do Sul, Dept Comp, BR-96815900 Santa Cruz Do Sul, RS, Brazil

[4] Univ Santa Cruz do Sul, Programa Posgrad Sistemas & Proc Ind, BR-96815900 Santa Cruz Do Sul, RS, Brazil

[5] Univ Santa Cruz do Sul, Programa Posgrad Tecnol Ambiental, BR-96815900 Santa Cruz Do Sul, RS, Brazil

关键词: Crude oil;    Chloride determination;    Colorimetric analysis;    Portable devices;   

DOI  :  10.1016/j.fuel.2020.119941

来源: Elsevier

【 摘 要 】

A digital image-based (DIB) method using colorimetry via a portable device is proposed for salt determination in crude oil. Chloride was extracted to an aqueous phase, followed by colorimetric quantification using digital images. A USB camera was attached to a homemade 3D-printed chamber with controlled light intensity. The images were converted into red, green, and blue (RGB) histograms, and a partial least squares regression (PLS) model was constructed using the free PhotoMetrix UVC app. The experimental parameters were optimized, as the ratio between silver nitrate and the potassium chromate, the lighting, the volume of solution in the measurement chamber, the focal distance, and the pH effect. A miniaturized extraction method was developed for sample preparation, and the main parameters were evaluated: sample mass, time, temperature, solvent, or the use of a demulsifier and its amount. The PLS regression model was evaluated in terms of the coefficient of determination (R-2), the root mean squared error of calibration (RMSEC), the root mean squared error of cross validation (RMSECV) and the root mean squared error of prediction (RMSEP). The detection limit was 69 mg L-1 (0.034 mg g(-1) using 10 g of sample). No differences were observed (p < 0.05) when comparing the results from the DIB method with the reference values. The extraction method's simplicity combined with the digital image-based colorimetric analysis allowed an easy-to-use and environmentally friendly method. Other important advantages include low cost, the possibility to be portable, and high throughput in comparison to standard methods.

【 授权许可】

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