Conformal growth of low friction HfBxCy hard coatings

THIN SOLID FILMS

卷:592

Article

Mohimi, E.¹  Ozkan, T.²  Babar, S.¹  Polycarpou, A. A.²  Abelson, J. R.¹ 

[1] Univ Illinois, Dept Mat Sci & Engn, Urbana, IL 61801 USA

[2] Univ Illinois, Dept Mech Sci & Engn, Urbana, IL 61801 USA

关键词: Hafnium borocarbide;    CVD;    Hard coating;    Low friction;    Conformal coating;   

DOI  :  10.1016/j.tsf.2015.09.018

来源: Elsevier

【 摘 要 】

Thin films of HfBxCy are deposited in a cold wall CVD apparatus using Hf(BH4)(4) precursor and 3,3-dimethyl-1-butene, (CH3)(3)CCH=CH2, as a controllable source of carbon, at substrate temperatures of 250-600 degrees C. As-deposited films grown at 250 degrees C are highly conformal (e.g., in a very deep trench, the step coverage is above 90% at a depth/width of 30: 1), exhibit dense microstructure, and appear amorphous in X-ray diffraction. Increasing the carbon content from 5 to 21 at.% decreases the hardness from 21 to 9 GPa and the reduced modulus from 207 to 114 GPa. Films grown at 600 degrees C with carbon contents of 28 and 35 at.% exhibit enhanced hardness of 25 and 23 GPa, and reduced modulus of 211 and 202 GPa, respectively. Annealing the 300 degrees C grown films at 700 degrees C affords a nanocrystalline structure with improvedmechanical properties. For films with the highest and lowest carbon contents, respectively: the coefficient of sliding friction is in the range of 0.05-0.08 and the H/E and H-3/E-2 ratios range from 0.08-0.11 and 0.15-0.40. These values indicate that C-containing films should exhibit improved wear performance in tribological applications. (C) 2015 Elsevier B.V. All rights reserved.

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