The quantum canonical ensemble in phase space

PHYSICA D-NONLINEAR PHENOMENA

卷:424

Article

Ozorio de Almeida, Alfredo M.¹  Ingold, Gert-Ludwig²  Brodier, Olivier³ 

[1] Ctr Brasileiro Pesquisas Fis, Rua Xavier Sigaud 150, BR-22290180 Rio De Janeiro, RJ, Brazil

[2] Univ Augsburg, Inst Phys, Univ Str 1, D-86135 Augsburg, Germany

[3] Univ Tours, Inst Denis Poisson, Campus Grandmont, F-37200 Tours, France

关键词: Wigner function;    Weyl representation;    Quantum canonical ensemble;    Semiclassical limit;   

DOI  :  10.1016/j.physd.2021.132951

来源: Elsevier

【 摘 要 】

The density operator for a quantum system in thermal equilibrium with its environment depends on Planck's constant, as well as the temperature. At high temperatures, the Weyl representation, that is, the thermal Wigner function, becomes indistinguishable from the corresponding classical distribution in phase space, whereas the low temperature limit singles out the quantum ground state of the system's Hamiltonian. In all regimes, thermal averages of arbitrary observables are evaluated by integrals, as if the thermal Wigner function were a classical distribution. The extension of the semiclassical approximation for quantum propagators to an imaginary thermal time, bridges the complex intervening region between the high and the low temperature limit. This leads to a simple quantum correction to the classical high temperature regime, irrespective of whether the motion is regular or chaotic. A variant of the full semiclassical approximation with a real thermal time, though in a doubled phase space, avoids any search for particular trajectories in the evaluation of thermal averages. The double Hamiltonian substitutes the stable minimum of the original system's Hamiltonian by a saddle, which eliminates local periodic orbits from the stationary phase evaluation of the integrals for the partition function and thermal averages. (C) 2021 Elsevier B.V. All rights reserved.

【 授权许可】

Free