Catalytic intramolecular decarbonylative coupling of 3-aminocyclobutenones and alkenes: a unique approach to [3.1.0] bicycles

TETRAHEDRON

卷:71

Article

Zhou, Xuan¹  Zafar, Imran¹  Dong, Guangbin¹ 

[1] Univ Texas Austin, Dept Chem, Austin, TX 78712 USA

关键词: C-C cleavage;    Cyclobutenone;    Rhodium catalysis;    Decarbonylation;    Cyclopropanation;   

DOI  :  10.1016/j.tet.2015.02.087

来源: Elsevier

【 摘 要 】

Here we describe a rhodium-catalyzed intramolecular decarbonylative coupling between 3-aminocyclobutenones and alkenes for synthesis of substituted [3.1.0] bicycles. This transformation represents a formal cyclopropanation reaction, in which the cyclobutenones serve as a one-carbon-unit synthon. (C) 2015 Elsevier Ltd. All rights reserved.

【 授权许可】

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