Organoboron chemistry comes to light: Recent advances in photoinduced synthetic approaches to organoboron compounds

TETRAHEDRON

卷:75

Article

Nguyen, Viet D.¹  Nguyen, Vu T.¹  Jin, Shengfei¹  Dang, Hang T.¹  Larionov, Oleg V.¹ 

[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

关键词: Borylation;    Carboboration;    Diboron reagents;    Photochemistry;    Organoboron compounds;    Rearrangements;    Ring contraction;   

DOI  :  10.1016/j.tet.2018.12.040

来源: Elsevier

【 摘 要 】

Photoinduced synthetic approaches to organoboron compounds have attracted significant attention in the recent years. Photochemical activation of organic molecules enables generation of reactive intermediates from a variety of precursors, resulting in borylation methods with improved and broader substrate scopes. The review summarizes recent developments in the area of photoinduced reactions of organoboron compounds with an emphasis on borylation of haloarenes, amine derivatives, and redox-active esters of carboxylic acids, as well as photoinduced rearrangements of organoboron compounds and photoinduced synthesis of organoboron compounds from alkenes and alkynes. (C) 2018 Elsevier Ltd. All rights reserved.

【 授权许可】

Free